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Chromate vs. Dichromate — What's the Difference?

Edited by Tayyaba Rehman — By Fiza Rafique — Updated on September 28, 2023
Chromate and Dichromate are anions related to chromium, a metallic element. While both are associated with the element's different oxidation states, they exhibit distinct chemical properties and behaviors. ​ ​
Chromate vs. Dichromate — What's the Difference?

Difference Between Chromate and Dichromate

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Key Differences

These two anions can interconvert based on the pH of the solution. In acidic conditions, Chromate ions can transform into Dichromate ions, while in basic conditions, the opposite reaction takes place.
Both Chromate and Dichromate are oxidizing agents, but they differ in strength and reactivity. Their distinct structures and electron configurations contribute to their unique chemical behaviors.
From an environmental and health perspective, both Chromate and Dichromate are considered toxic and can be harmful if ingested, inhaled, or contacted. Proper care and safety measures should be observed when working with either compound.

Comparison Chart

Chromium Atoms

One
Two

Oxidation State

+6
+6
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Color (in solution)

Yellow
Orange

Behavior in Acidic pH

Converts to Dichromate
Remains as Dichromate

Compare with Definitions

Chromate

An anion derived from chromium.
The yellow color in the solution indicates the presence of Chromate ions.

Dichromate

A compound with a distinctive orange hue.
The presence of Dichromate gives the solution its orange color.

Chromate

An oxidizing agent related to chromium.
Chromate can oxidize ferrous ions to ferric ions.

Dichromate

A toxic and carcinogenic compound.
Exposure to Dichromate should be minimized due to its health risks.

Chromate

A salt or ester of chromic acid.
Sodium chromate is a common Chromate salt.

Dichromate

A potent oxidizing agent.
Dichromate can readily oxidize many compounds in chemical reactions.

Chromate

A toxic compound often found in paints and coatings.
The use of Chromate in paints is now restricted due to health concerns.

Dichromate

The anionic divalent group, Cr2O7, or a compound containing it, usually having a characteristic orange-red color. Also called bichromate.

Chromate

The anionic divalent CrO4 group or a compound containing it.

Dichromate

(chemistry) any salt of dichromic acid; in solution the orange dichromate anion (Cr2O72-) is in equilibrium with the yellow chromate anion (CrO42-), the relative amount of each ion depending on the pH; they are both very powerful oxidizing agents

Chromate

(inorganic chemistry) any salt of chromic acid; in solution the yellow chromate anion (CrO42-) is in equilibrium with the orange dichromate anion (Cr2O72−), the relative amount of each ion depending on the pH; they are both very powerful oxidizing agents

Dichromate

A salt of chromic acid containing two equivalents of the acid radical to one of the base; - called also bichromate.

Chromate

To treat with a chromate solution

Dichromate

A salt of the hypothetical dichromic acid

Chromate

A salt of chromic acid.

Chromate

Any salt or ester of chromic acid

Common Curiosities

Can Chromate and Dichromate interconvert?

Yes, their conversion is pH-dependent. Chromate can become Dichromate in acidic conditions and vice versa in basic conditions.

Which is more oxidizing, Chromate or Dichromate?

Both are oxidizing agents, but their strengths can vary based on the conditions.

Why are Chromate and Dichromate colored?

Their color arises from the electronic transitions within the chromium ions.

Do Chromate and Dichromate have applications in industry?

Yes, they have uses in pigments, metal treatments, and as laboratory reagents.

Can I use either Chromate or Dichromate for oxidation reactions?

Yes, but the suitability might depend on the specific reaction.

Do Chromate and Dichromate have different chemical properties?

Yes, their differing structures and oxidation states give them unique properties.

How do Chromate and Dichromate affect human health?

They can be carcinogenic and harmful if ingested, inhaled, or contacted.

Are Chromate and Dichromate safe to handle?

Both are toxic and can pose health risks; precautions are necessary.

What's the significance of the oxidation state in Chromate and Dichromate?

It dictates their reactivity, electronic structure, and interaction with other compounds.

Are Chromate and Dichromate related to chromium?

Yes, both are anions related to different oxidation states of chromium.

How can I differentiate between Chromate and Dichromate in a solution?

Typically, Chromate solutions are yellow while Dichromate solutions are orange.

Which is more prevalent in nature, Chromate or Dichromate?

Their prevalence can depend on the pH and oxidation conditions of the environment.

Can Chromate and Dichromate be found in consumer products?

They have been used in products like paints, but many uses are now restricted.

Are Chromate and Dichromate considered environmental pollutants?

Yes, due to their toxicity, their release into the environment is a concern.

Are there any safety guidelines for working with Chromate and Dichromate?

Yes, always refer to safety data sheets and use personal protective equipment when handling them.

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Author Spotlight

Written by
Fiza Rafique
Fiza Rafique is a skilled content writer at AskDifference.com, where she meticulously refines and enhances written pieces. Drawing from her vast editorial expertise, Fiza ensures clarity, accuracy, and precision in every article. Passionate about language, she continually seeks to elevate the quality of content for readers worldwide.
Tayyaba Rehman is a distinguished writer, currently serving as a primary contributor to askdifference.com. As a researcher in semantics and etymology, Tayyaba's passion for the complexity of languages and their distinctions has found a perfect home on the platform. Tayyaba delves into the intricacies of language, distinguishing between commonly confused words and phrases, thereby providing clarity for readers worldwide.

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