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Silicone vs. Siloxane — What's the Difference?

Edited by Tayyaba Rehman — By Fiza Rafique — Updated on September 30, 2023
Silicone is a synthetic material made from silicon, oxygen, carbon, and hydrogen. Siloxane is a specific chemical compound with a backbone of silicon-oxygen alternation. All silicones contain siloxane units, but not all siloxanes form silicones.
Silicone vs. Siloxane — What's the Difference?

Difference Between Silicone and Siloxane

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Key Differences

Silicone is a versatile and widely used synthetic polymer with a range of applications from medical devices to kitchenware. Its primary components include silicon, oxygen, carbon, and hydrogen. Siloxane, by contrast, is a foundational chemical structure characterized by a repeating silicon-oxygen bond, forming the backbone of silicones.
In the world of chemistry, silicones refer to a family of polymers that possess a unique flexibility, resistance to temperature, and hydrophobicity. These properties are attributed to the presence of siloxane linkages in their structure. Siloxanes, therefore, are not standalone materials but are integral parts of larger silicone molecules.
When discussing the utility and functionality of silicone, it often comes down to the inherent properties provided by the siloxane units. The alternating silicon and oxygen atoms in siloxane give silicones their renowned flexibility and resilience, crucial for many applications.

Comparison Chart

Definition

A synthetic polymer with a variety of formulations
A specific chemical structure with Si-O bonds

Composition

Contains silicon, oxygen, carbon, and hydrogen
Primarily silicon and oxygen
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Utility

Versatile material with wide applications
Structural unit within silicones

Standalone Material

Yes, can be produced in various forms
No, represents a bond or linkage within silicones

Scope

Broad category of materials
Specific type of linkage or structure

Compare with Definitions

Silicone

Material known for its heat resistance and flexibility.
Silicone spatulas can withstand high cooking temperatures.

Siloxane

A chemical compound with repeating silicon-oxygen bonds.
Siloxane units provide flexibility to silicone products.

Silicone

A synthetic polymer with diverse formulations.
Silicone bakeware is popular for its non-stick properties.

Siloxane

A linkage or bond within silicone molecules.
Siloxane structures make silicone resistant to heat.

Silicone

An inert and biocompatible material.
Silicone is often found in medical devices due to its biocompatibility.

Siloxane

Alternating sequence of silicon and oxygen atoms.
The siloxane bond is the essence of silicone's unique properties.

Silicone

Polymer with water-repellent properties.
Rain boots made of silicone keep feet dry.

Siloxane

A component that defines the resilience of silicone.
Due to the siloxane structures, silicone products last long.

Silicone

A silicone or polysiloxane is a polymer made up of siloxane (−R2Si−O−SiR2−, where R = organic group). They are typically colorless, oils or rubber-like substances.

Siloxane

The foundational structure of silicones.
The properties of silicone are often attributed to its siloxane linkages.

Silicone

Any of a class of synthetic materials which are polymers with a chemical structure based on chains of alternate silicon and oxygen atoms, with organic groups attached to the silicon atoms. Such compounds are typically resistant to chemical attack and insensitive to temperature changes and are used to make rubber and plastics and in polishes and lubricants
Silicone rubber
Modern plastics and silicones

Siloxane

A siloxane is a functional group in organosilicon chemistry with the Si−O−Si linkage. The parent siloxanes include the oligomeric and polymeric hydrides with the formulae H(OSiH2)nOH and (OSiH2)n.

Silicone

Join or otherwise treat (something) with a silicone
The raised planting shelf could be siliconed to the back of the tank

Siloxane

Any of a class of chemical compounds of silicon, oxygen, and hydrogen, based on the repeating structural unit H2SiO.

Silicone

Any of a large group of oligomers and polymers based on the structural unit R2SiO, where R is an organic group, characterized by wide-range thermal stability, high lubricity, extreme water repellence, and physiological inertness and used in adhesives, lubricants, protective coatings, paints, electrical insulation, synthetic rubber, and prosthetic replacements for body parts.

Siloxane

(chemistry) Any of a class of compound having a short repeating unit of silicon and oxygen atoms (either in a chain or a ring), typically with organic side chains

Silicone

(chemistry) Any of a class of inert, semi-inorganic polymeric compounds (polysiloxanes), that have a wide range of thermal stability and extreme water repellence, used in a very wide range of industrial applications, and in prosthetic replacements for body parts.

Siloxane

Any of a large class of compounds that have alternate silicon and oxygen atoms

Silicone

(transitive) To join or treat (something) with a silicone-based product.
Silicone the bathtub to the tile

Silicone

To enhance or reconstruct (a body part) with a prosthesis containing silicone.

Silicone

Any of a large class of siloxanes that are unusually stable over a wide range of temperatures; used in lubricants and adhesives and coatings and synthetic rubber and electrical insulation

Silicone

A compound primarily made of silicon, oxygen, carbon, and hydrogen.
Silicone implants are commonly used in medical procedures.

Common Curiosities

Why is silicone used in cookware?

Due to its heat resistance and non-stick properties, both attributes related to siloxane structures.

Are siloxanes harmful?

Some siloxanes are under scrutiny for environmental reasons, but they vary in their impacts.

Does siloxane exist on its own?

Not typically; it's a structural unit within silicones.

Are all silicones the same?

No, they vary based on the arrangement and length of siloxane chains.

Can silicone melt?

It has a high heat resistance, but it can degrade at very high temperatures.

Is silicone the same as silicon?

No, silicon is a natural element, while silicone is a synthetic polymer containing siloxane units.

Is silicone a natural material?

No, silicone is a synthetic material.

Why is silicone used in cosmetics?

Its smooth texture and water-repellent properties, attributed to siloxane, make it desirable.

What makes silicones flexible?

The siloxane linkages provide flexibility to the polymer.

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Author Spotlight

Written by
Fiza Rafique
Fiza Rafique is a skilled content writer at AskDifference.com, where she meticulously refines and enhances written pieces. Drawing from her vast editorial expertise, Fiza ensures clarity, accuracy, and precision in every article. Passionate about language, she continually seeks to elevate the quality of content for readers worldwide.
Tayyaba Rehman is a distinguished writer, currently serving as a primary contributor to askdifference.com. As a researcher in semantics and etymology, Tayyaba's passion for the complexity of languages and their distinctions has found a perfect home on the platform. Tayyaba delves into the intricacies of language, distinguishing between commonly confused words and phrases, thereby providing clarity for readers worldwide.

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