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Supernatant vs. Precipitate — What's the Difference?

Edited by Tayyaba Rehman — By Fiza Rafique — Updated on September 27, 2023
The supernatant is the clear liquid left behind after a precipitate has settled, while a precipitate is the solid that forms and settles out of a solution.
Supernatant vs. Precipitate — What's the Difference?

Difference Between Supernatant and Precipitate

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Key Differences

The supernatant refers to the clear, upper layer of liquid that remains after a solid, known as the precipitate, has settled out of a solution. This separation typically occurs after centrifugation or simply letting a solution stand undisturbed.
In chemical reactions, when certain solutions are mixed, a solid can form and settle at the bottom. This solid is called the precipitate, while the remaining clear liquid on top is the supernatant.
The supernatant often contains solutes that remain dissolved in the liquid, while the precipitate contains the substances that have come out of the solution due to a change in conditions, like temperature or pH.
Analytical chemists and researchers frequently use the terms supernatant and precipitate. After a reaction, the precipitate is often collected and analyzed, while the supernatant might be discarded or further processed.
In conclusion, while the supernatant describes the clear liquid above a settled solid, the precipitate denotes the solid particles that have settled out from the solution.
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Comparison Chart

State of Matter

Liquid
Solid

Position in Solution

Top or above the settled matter
Settled at the bottom or within the liquid

Formed from

Remaining solvents and dissolved solutes
Insoluble compounds or particles

Clarity

Clear
Opaque, solid

Typical Treatment

Often discarded or further processed
Collected and analyzed

Compare with Definitions

Supernatant

The clear liquid above a settled solid.
After centrifugation, the cells formed a pellet and the clear supernatant was carefully removed.

Precipitate

The solid formed in a solution due to a chemical reaction.
When silver nitrate and sodium chloride mix, a white precipitate of silver chloride forms.

Supernatant

Liquid remaining after precipitation.
The supernatant was siphoned off, leaving behind the sediment.

Precipitate

To cause to happen, especially suddenly or prematurely
An announcement that precipitated a political crisis.

Supernatant

Residual liquid post-centrifugation.
The DNA was found in the supernatant, not in the solid phase.

Precipitate

To cause to fall down from a height; hurl downward
"The finest bridge in all Peru broke and precipitated five travelers into the gulf below" (Thornton Wilder).

Supernatant

The solution atop the precipitate in a container.
The chemist carefully pipetted the supernatant to avoid disturbing the crystals below.

Precipitate

To put suddenly into a certain state or condition
"He was like a man who had never known liberty and was all at once precipitated into it" (Taylor Caldwell).

Supernatant

Liquid fraction separated from the solid component.
The supernatant contained valuable enzymes for further study.

Precipitate

(Meteorology) To cause (a form of water, as rain or snow) to fall from the air.

Supernatant

Denoting the liquid lying above a solid residue after crystallization, precipitation, centrifugation, or other process
Carefully transfer the supernatant fluid into a 15 ml centrifuge tube

Precipitate

(Chemistry) To cause (a solid substance) to be separated from a solution.

Supernatant

A volume of supernatant liquid
The supernatants were filtered and analysed

Precipitate

(Meteorology) To fall from the air as a form of water, such as rain or snow.

Supernatant

Floating on the surface.

Precipitate

(Chemistry) To be separated from a solution as a solid.

Supernatant

The clear fluid above a sediment or precipitate.

Precipitate

Moving rapidly and heedlessly; speeding headlong.

Supernatant

Lying or floating above a denser fluid, or above a solid sediment or precipitate (which has been separated by crystallisation, centrifugation etc.).

Precipitate

Acting with or marked by excessive haste and lack of due deliberation.

Supernatant

The liquid that lies above a sediment or precipitate; supernate

Precipitate

Occurring suddenly or unexpectedly.

Supernatant

Material that floats on the surface of a liquid

Precipitate

(Chemistry) A solid or solid phase separated from a solution.

Supernatant

Swimming above; floating on the surface; as, oil supernatant on water.

Precipitate

A product resulting from a process, event, or course of action.

Supernatant

The liquid remaining after solids suspended in the liquid have been sedimented by gravity or by centrifugation. Contrasted with the solid sediment, or (in centrifugation) the pellet.

Precipitate

(transitive) To make something happen suddenly and quickly.
To precipitate a journey, or a conflict
It precipitated their success

Supernatant

A liquid lying above a sediment (floating on the surface)

Precipitate

(transitive) To throw an object or person from a great height.

Supernatant

Of a liquid; floating on the surface above a sediment or precipitate;
The supernatant fat was skimmed off

Precipitate

(transitive) To send violently into a certain state or condition.
We were precipitated into a conflict

Precipitate

To come out of a liquid solution into solid form.
Adding the acid will cause the salt to precipitate.

Precipitate

To separate a substance out of a liquid solution into solid form.

Precipitate

To have water in the air fall to the ground, for example as rain, snow, sleet, or hail; be deposited as condensed droplets.
It will precipitate tomorrow, but we don't know whether as rain or snow.

Precipitate

(transitive) To cause (water in the air) to condense or fall to the ground.

Precipitate

(intransitive) To fall headlong.

Precipitate

(intransitive) To act too hastily; to be precipitous.

Precipitate

Headlong; falling steeply or vertically.

Precipitate

Very steep; precipitous.

Precipitate

With a hasty impulse; hurried; headstrong.

Precipitate

Moving with excessive speed or haste; overly hasty.
The king was too precipitate in declaring war.
A precipitate case of disease

Precipitate

Performed very rapidly or abruptly.

Precipitate

A product resulting from a process, event, or course of action

Precipitate

(chemistry) a solid that exits the liquid phase of a solution

Precipitate

Overhasty; rash; as, the king was too precipitate in declaring war.

Precipitate

Lacking due deliberation or care; hurried; said or done before the time; as, a precipitate measure.

Precipitate

Falling, flowing, or rushing, with steep descent; headlong.
Precipitate the furious torrent flows.

Precipitate

Ending quickly in death; brief and fatal; as, a precipitate case of disease.

Precipitate

An insoluble substance separated from a solution in a concrete state by the action of some reagent added to the solution, or of some force, such as heat or cold. The precipitate may fall to the bottom (whence the name), may be diffused through the solution, or may float at or near the surface.

Precipitate

Atmospheric moisture condensed as rain or snow, etc.; same as precipitation{5}.

Precipitate

To throw headlong; to cast down from a precipice or height.
She and her horse had been precipitated to the pebbled region of the river.

Precipitate

To urge or press on with eager haste or violence; to cause to happen, or come to a crisis, suddenly or too soon; as, precipitate a journey, or a conflict.
Back to his sight precipitates her steps.
If they be daring, it may precipitate their designs, and prove dangerous.

Precipitate

To separate from a solution, or other medium, in the form of a precipitate; as, water precipitates camphor when in solution with alcohol.
The light vapor of the preceding evening had been precipitated by the cold.

Precipitate

To dash or fall headlong.
So many fathom down precipitating.

Precipitate

To hasten without preparation.

Precipitate

A precipitated solid substance in suspension or after settling or filtering

Precipitate

Separate as a fine suspension of solid particles

Precipitate

Bring about abruptly;
The crisis precipitated by Russia's revolution

Precipitate

Fall from clouds;
Rain, snow and sleet were falling
Vesuvius precipitated its fiery, destructive rage on Herculaneum

Precipitate

Fall vertically, sharply, or headlong;
Our economy precipitated into complete ruin

Precipitate

Hurl or throw violently;
The bridge broke and precipitated the train into the river below

Precipitate

Done with very great haste and without due deliberation;
Hasty marriage seldom proveth well
Hasty makeshifts take the place of planning
Rejected what was regarded as an overhasty plan for reconversion
Wondered whether they had been rather precipitate in deposing the king

Precipitate

Insoluble substance that settles out of a solution.
The experiment resulted in a yellow precipitate at the bottom of the flask.

Precipitate

Solid substance separated from a liquid phase.
The sudden temperature change caused a precipitate to form in the liquid.

Precipitate

Matter that has transitioned from dissolved to solid form.
By adjusting the pH, we can force certain compounds to precipitate out.

Precipitate

Resultant solid after a solute exceeds its solubility.
The saturated solution yielded a crystalline precipitate upon cooling.

Common Curiosities

Why do precipitates form in solutions?

Precipitates form when the solubility of a substance is exceeded or due to a chemical reaction that produces an insoluble compound.

What is a precipitate?

A precipitate is the solid that forms and settles out of a solution.

What is a supernatant?

The supernatant is the clear liquid left behind after a precipitate has settled.

Can changes in temperature cause precipitation?

Yes, changes in temperature can affect solubility, leading to the formation of a precipitate.

Is the supernatant always clear?

Ideally, the supernatant is clear, but it might be slightly cloudy if some fine precipitate remains suspended.

Is the supernatant always discarded?

No, depending on the purpose of the experiment or process, the supernatant might be further analyzed or processed.

How is the supernatant separated from the precipitate?

The supernatant can be separated from the precipitate through decanting, pipetting, or centrifugation.

Can the supernatant contain dissolved solutes?

Yes, the supernatant can still contain solutes that remain dissolved in the liquid.

Can the supernatant be colored?

Yes, the supernatant can be colored if it contains colored dissolved solutes.

Can precipitates redissolve in a solution?

Some precipitates can redissolve under changed conditions like temperature or pH, while others remain insoluble.

How can a precipitate be collected?

A precipitate can be collected by filtration or centrifugation and then dried.

How do researchers ensure that all the precipitate has settled?

Techniques like centrifugation or allowing the solution to stand for an extended period help in settling all the precipitate.

Are precipitates always solids?

Generally, precipitates refer to solids that form in solutions, but in broader contexts, it can also refer to liquids that separate out.

How can one increase the size of precipitate particles?

Slow addition of reactants or gentle stirring can lead to larger precipitate particles.

Why is it important to remove all supernatant from a precipitate?

Complete removal ensures that no contaminants or unwanted solutes are carried forward with the precipitate.

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Author Spotlight

Written by
Fiza Rafique
Fiza Rafique is a skilled content writer at AskDifference.com, where she meticulously refines and enhances written pieces. Drawing from her vast editorial expertise, Fiza ensures clarity, accuracy, and precision in every article. Passionate about language, she continually seeks to elevate the quality of content for readers worldwide.
Tayyaba Rehman is a distinguished writer, currently serving as a primary contributor to askdifference.com. As a researcher in semantics and etymology, Tayyaba's passion for the complexity of languages and their distinctions has found a perfect home on the platform. Tayyaba delves into the intricacies of language, distinguishing between commonly confused words and phrases, thereby providing clarity for readers worldwide.

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